What Expression Blend was
Expression Blend was Microsoft's design tool for XAML interfaces. It was announced as Expression Interactive Designer, renamed to Expression Blend in December 2006, reached its first public preview on 24 January 2007 and shipped that April. Its purpose was to let a designer work on a Windows Presentation Foundation or Silverlight interface visually, producing the same XAML a developer would otherwise hand-write, so that the two roles could work on one artefact instead of exchanging mockups.
The product sat inside Microsoft Expression Studio alongside Expression Web, Expression Design and Expression Encoder. Version 3, released in 2009, is the release most contemporary reviews discuss, and it is the version that introduced SketchFlow, a rapid-prototyping mode that produced clickable, annotatable prototypes rather than finished markup. Expression Studio reached its final release, version 4.0, on 7 June 2010.
In December 2012 Microsoft discontinued the standalone Expression suite. Expression Web and Expression Design were retired outright; Blend was moved inside Visual Studio and continued as Blend for Visual Studio. That is the pivot that makes the tool confusing to research: the same name describes a standalone product with its own release history and, afterwards, a component of a much larger one.